May 3, 2013

‘Going negative’ pays for nanotubes




Rice University lab finds possible keys to better nanofibers, films

A Rice University laboratory’s cagey strategy turns negatively charged carbon nanotubes into liquid crystals that could enhance the creation of fibers and films.

The latest step toward making macro materials out of microscopic nanotubes depends on cage-like crown ethers that capture potassium cations. Negatively charged carbon nanotubes associate with potassium cations to maintain their electrical neutrality. In effect, the ethers help strip these cations from the surface of the nanotubes, resulting into a net charge that helps counterbalance the electrical van der Waals attraction that normally turns carbon nanotubes into an unusable clump.